Correction: “Give me five” – an amino imidazoline-2-imine ligand stabilises the first neutral five-membered cyclic triel(i) carbenoids
نویسندگان
چکیده
Correction for ‘“Give me five” – an amino imidazoline-2-imine ligand stabilises the first neutral five-membered cyclic triel(i) carbenoides’ by Lars Denker et al., Chem. Commun., 2021, 57, 2816–2819, DOI: 10.1039/D1CC00010A.
منابع مشابه
Molecular polarizability anisotropy of some five-membered cyclic imides
0022-2860/$ see front matter 2011 Elsevier B.V. A doi:10.1016/j.molstruc.2011.04.016 ⇑ Corresponding author. E-mail address: [email protected] (O.V. Dipole moments (l), molar Kerr constants (mK) and molecular polarizabilities of several five-membered ring imides and a number of model compounds were measured. Various models for determination of molecular polarizability and mK values wer...
متن کاملSynthesis of five- and six-membered cyclic organic peroxides: Key transformations into peroxide ring-retaining products
The present review describes the current status of synthetic five and six-membered cyclic peroxides such as 1,2-dioxolanes, 1,2,4-trioxolanes (ozonides), 1,2-dioxanes, 1,2-dioxenes, 1,2,4-trioxanes, and 1,2,4,5-tetraoxanes. The literature from 2000 onwards is surveyed to provide an update on synthesis of cyclic peroxides. The indicated period of time is, on the whole, characterized by the devel...
متن کاملBromocyclization of Unsaturated Oximes. Synthesis of Five-Membered Cyclic Nitrones (Pyrroline N-Oxides)* [1]
The cyclization of a ribose-derived pentenose oxime with various halogen electrophiles showed bromine to be the most effective reagent, leading to 80% of L-lyxo/D-ribo-pyrroline N-oxides in an 84:16 diastereomeric ratio. In order to explore the scope of this facile process, several other γ ,δ unsaturated oximes were submitted to this reaction. Depending on the substitution pattern, 23 – 87%, yi...
متن کاملSynthesis of five-membered cyclic ethers by reaction of 1,4-diols with dimethyl carbonate.
The reaction of 1,4-diols with dimethyl carbonate in the presence of a base led to selective and high-yielding syntheses of related five-membered cyclic ethers. This synthetic pathway has the potential for a wide range of applications. Distinctive cyclic ethers and industrially relevant compounds were synthesized in quantitative yield. The reaction mechanism for the cyclization was investigated...
متن کاملA bulky biaryl phosphine ligand allows for palladium-catalyzed amidation of five-membered heterocycles as electrophiles.
Palladium-catalyzed amidation of five-membered heterocyclic bromides that contain multiple heteroatoms was achieved for the first time using the Pd/1 catalyst system. This system allows for efficient access to N-arylated imidazoles, pyrazoles, thiazoles, pyrroles, and thiophenes in moderate to excellent yield. Experimental results and DFT calculations point to the need for electron-rich and esp...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Chemical Communications
سال: 2021
ISSN: ['1359-7345', '1364-548X']
DOI: https://doi.org/10.1039/d1cc90120f